
Benzene is nonpolar because it is a symmetrical molecule in which all the bond cancel.
The structure of benzene is
It is a flat molecule with the shape of a regular hexagon.
We could say that benzene is nonpolar because it is a hydrocarbon that contains only ##C-C## and ##C-H## bonds, and hydrocarbons are nonpolar.
But ##C## is slightly more electronegative than ##H## (by 0.35 units), so a ##C-H## bond is very slightly polar and has a small dipole moment.
However, each ##C-H## bond has a partner that points in exactly the opposite direction.
The bond dipoles cancel exactly, so benzene has a zero dipole moment.
This makes benzene a nonpolar molecule.
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